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Kanto

HP
Cerulean Cave Entrance: 5 x wobbuffet(10 EVs) / 5 x lickitung(10 EVs) Leppa needed
Route 14: 5 x nidorina(10 EVs) Cut needed
Attack
Route 15: 5 x nidorino(10 EVs)
Defense
Victory Road: 5 x sandslash(10 EVs) / 5 x marowak(10 EVs)
Cape Brink(Two Island): 5 x slowbro(10 EVs)
Pattern Bush(Six Island): 5 x metapod(10 EVs) / 5 x kakuna(10 EVs) Leppa Needed
Special Attack
Cape Brink(Two Island): 5 x golduck(10 EVs) Surf Needed
Cerulean Cave: 5 x golduck(10 EVs) Surf & Leppa needed
Special Defense
Seven Island: 5 x tentacruel(10 EVs) Surf Needed
Speed
Five Isle Meadow: 5 x pidgeotto(10 EVs)
Water Path(Six Island): 5 x persian(10 EVs)

Johto

HP
Route 44: 5 x lickitung(10 EVs)
Attack
Cliff Cave: 5 x kingler(10 EVs) / 5 x machoke(10 EVs) Leppa Needed
Defense
Route 26: 5 x sandslash(10 EVs)
Special Attack
Special Defense
Route 26: 5 x tentacruel(10 EVs) Surf Needed
Speed
Blackthorn City(Behind Gym): 5 x poliwhirl(10 EVs) Surf Needed
Mt.Silver: 5 x poliwhirl(10 EVs) Surf Needed

Hoenn

HP
Route 114: 5 x marill(10 EVs) Surf Needed
Victory Road(Pokemon League Side): 5 x hariyama(10 EVs)
Desert Underpass: 5 x loudred(10 EVs) Leppa Needed
Defense
Ever Grande City(Down): 5 x pelipper(10 EVs) Surf Needed
Special Attack
Route 119: 5 x gloom(10 EVs)
Special Defense
Battle Frontier: 5 x tentacruel(10 EVs) Surf Needed
Speed
Route 121: 5 x linoone(10 EVs)

Sinnoh

HP
Route 230: 5 x sealeo(10 EVs) Surf Needed
Attack
Victory Road: 5 x rhydon(10 EVs)
Route 211: 5 x machoke(10 EVs)
Defense
Route 222: 5 x pelipper(10 EVs) Surf Needed
Special Attack
Resort Area: 5 x golduck(10 EVs) Surf Needed
Special Defense
Victory Road: 5 x tentacruel(10 EVs) Surf Needed
Speed
Route 222: 5 x floatzel(10 EVs) / 5 x electabuzz(10 EVs)

Unova

HP
Route 10(Dark Grass): 5 x amoonguss(10 EVs)
Attack
Route 10: 5 x bouffalant(10 EVs)
Defense
Undella Bay: 5 x pelipper(10 EVs) Surf Needed
Special Attack
Route 9: 5 x duosion(10 EVs)
Route 11: 5 x golduck(10 EVs) Surf Needed
Victory Road: 5 x heatmor(10 EVs)
Special Defense
Route 9(Dark Grass): 5 x gothorita(10 EVs)
Undella Town: 5 x mantine(10 EVs) Surf Needed
Speed
Route 12: 5 x rapidash(10 EVs)